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Appendix A
Hazardous Materials Table:
Postal Service Mailability Guide

The mailing information in this table is based on the DOT Hazardous Materials Table in 49 CFR 172.101 (dated October 1, 1998, and the revisions published in Federal Register 10742, dated March 5, 1999). The information is modified to identify the mailability of each hazardous material based on Postal Service mailing regulations. This table identifies the mailability of hazardous materials for domestic mail only. Almost no hazardous materials are permitted in international mail. For information on mailability in international mail, see Chapter 6 and Exhibit 621.1.

In the domestic mail, generally only those hazardous materials that can be reclassed as an ORM-D material and renamed with the proper shipping name of "Consumer Commodity" are eligible for mailing subject to the postal quantity limitations. The only exceptions are for the small number of materials listed in 322.

The columns in the table contain the following information:

Column (a): Lists the proper shipping name of the hazardous material in roman type. Text that appears in italic type is not part of the proper shipping name of the hazardous material and is listed for descriptive or reference purposes. Some listings direct the user to the preferred proper shipping name of a material listed elsewhere in the table. The text in this column closely matches the information in Column 2 of the Hazardous Materials Table in 49 CFR 172.101.

Column (b): Lists the assigned hazard class or division of the hazardous material. The entry "Forbidden" means the material may not be transported under any circumstances. The entry "n/a" means the material does not have an assigned hazard class. If this field is shaded, refer to the listing for the preferred proper shipping name cited in Column (a). The text in this column closely matches the information in Column 3 of the Hazardous Materials Table in 49 CFR 172.101.

Column (c): Lists the identification (ID) number assigned to the hazardous material. The number may be either a United Nations (UN) number or a North American (NA) number. This field is shaded if Column (a) directs the user to the listing for the preferred proper shipping name of the material, or if the entry in Column (b) is "Forbidden." The text in this column closely matches the information in Column 4 of the Hazardous Materials Table in 49 CFR 172.101.

Column (d): Lists the DOT Packing Group (PG) assignment for the hazardous material. Not all hazard classes have DOT Packing Group assignments. If this field contains "n/a," the material is in a hazard class that does not use Packing Group assignments. This field is shaded if Column (a) directs the user to the listing for the preferred proper shipping name of the material, or if the entry in Column (b) is "Forbidden." The text in this column closely matches the information in Column 5 of the Hazardous Materials Table in 49 CFR 172.101.

Column (e): Lists the mailability of the hazardous material according to Postal Service regulations. If the entry is "Prohibited," the material is nonmailable. If the entry cites a reference to this publication or the DMM, the material is subject to those requirements and restrictions. If the entry is "Only ORM-D," the material is mailable only if it can be reclassed as an ORM-D material and renamed with the proper shipping name of "Consumer Commodity" as permitted in 49 CFR. Mailable ORM-D materials cannot exceed the postal quantity limits specified in this publication and DMM C023. The mailer is responsible for correctly determining if the hazardous material is eligible to be reclassed as an ORM-D material. If assistance is needed, the mailer may request a ruling from the PCSC as provided in 215.2 and DMM C023.1.5. If the hazardous material is mailable in the domestic mail, refer to Column (f) and (g), as appropriate, to determine the applicable postal packaging instruction in Appendix C.

Column (f): Lists the packaging instruction in Appendix C that must be followed if the hazardous material is permitted in domestic mail via air transportation. This field is shaded if Column (a) directs the user to the listing for the preferred proper shipping name of the material, or if the hazardous material is prohibited from mailing as designated in Column (e). If the entry in this column is "Prohibited," the material is not permitted in domestic mail via air transportation.

Column (g): Lists the packaging instruction in Appendix C that must be followed if the hazardous material is permitted in domestic mail via surface transportation. This field is shaded if Column (a) directs the user to the listing for the preferred proper shipping name of the material, or if the hazardous material is prohibited from mailing as designated in Column (e). If the entry in this column is "Prohibited," the material is not permitted in domestic mail via surface transportation.

blank blank blank blank blank USPS Packaging Instructions
Hazardous Materials Descriptions and
Proper Shipping Names

(a)
Hazard Class
(b)
ID Number
(c)
DOT
PG
(d)
USPS
Mailability

(e)
Domestic Mail Air
(f)
Domestic Mail Surface
(g)
- A - blank blank blank blank blank blank
Accellerene, see p-Nitrosodimethylaniline blank blank blank blank blank blank
Accumulators, electric, see Batteries, wet etc. blank blank blank blank blank blank
Accumulators, pressurized, pneumatic or hydraulic (containing nonflammable gas) 2.2 NA1956 n/a Only ORM-D 2B 2B
Acetal 3 UN1088 II Only ORM-D Prohibited 3A
Acetaldehyde 3 UN1089 I Prohibited blank blank
Acetaldehyde ammonia 9 UN1841 III Only ORM-D 9C 9C
Acetaldehyde oxime 3 UN2332 III Only ORM-D Prohibited 3A
Acetic acid, glacial or Acetic acid solution, with more than 80 percent acid, by mass 8 UN2789 II Only ORM-D 8A 8A
Acetic acid solution, not less than 50 percent but not more than 80 percent acid, by mass 8 UN2790 II Only ORM-D per 348.22 8A 8A
Acetic acid solution, with more than 10 percent and less than 50 percent acid, by mass 8 UN2790 III Only ORM-D per 348.22 8A 8A
Acetic anhydride 8 UN1715 II Only ORM-D 8A 8A
Acetone 3 UN1090 II Only ORM-D Prohibited 3A
Acetone cyanohydrin, stabilized 6.1 UN1541 I Prohibited blank blank
Acetone oils 3 UN1091 II Only ORM-D Prohibited 3A
Acetonitrile 3 UN1648 II Only ORM-D Prohibited 3A
Acetyl acetone peroxide with more than 9 percent by mass active oxygen Forbidden blank blank Prohibited blank blank
Acetyl benzoyl peroxide, solid, or with more than 40 percent in solution Forbidden blank blank Prohibited blank blank
Acetyl bromide 8 UN1716 II Only ORM-D 8A 8A
Acetyl chloride 3 UN1717 II Prohibited blank blank
Acetyl cyclohexanesulfonyl peroxide, with more than 82 percent wetted with less than 12 percent water Forbidden blank blank Prohibited blank blank
Acetyl iodide 8 UN1898 II Only ORM-D 8A 8A
Acetyl methyl carbinol 3 UN2621 III Only ORM-D Prohibited 3A
Acetyl peroxide, solid, or with more than 25 percent in solution Forbidden blank blank Prohibited blank blank
Acetylene, dissolved 2.1 UN1001 n/a Prohibited blank blank
Acetylene (liquefied) Forbidden blank blank Prohibited blank blank
Acetylene silver nitrate Forbidden blank blank Prohibited blank blank
Acetylene tetrabromide, see Tetrabromoethane blank blank blank blank blank blank
Acid butyl phosphate, see Butyl acid phosphate blank blank blank blank blank blank
Acid, sludge, see Sludge, acid blank blank blank blank blank blank
Acridine 6.1 UN2713 III Only ORM-D 6A 6A
Acrolein dimer, stabilized 3 UN2607 III Only ORM-D Prohibited 3A
Acrolein, inhibited 6.1 UN1092 I Prohibited blank blank
Acrylamide 6.1 UN2074 III Only ORM-D 6A 6A
Acrylic acid, inhibited 8 UN2218 II Only ORM-D 8A 8A

Acrylonitrile, inhibited
3 UN1093 I Prohibited blank blank
Actuating cartridge, explosive, see Cartridges, power device blank blank blank blank blank blank
Adhesives, containing a flammable liquid 3 UN1133 I, II, III Only ORM-D Prohibited 3A
Adiponitrile 6.1 UN2205 III Only ORM-D 6A 6A
Aerosols, corrosive, Packing Group II or III, (each not exceeding 1 L capacity) 2.2 UN1950 n/a Only ORM-D 2B 2B
Aerosols, flammable (each not exceeding 1 L capacity) 2.1 UN1950 n/a Only ORM-D Prohibited 2A
Aerosols, flammable, n.o.s. (engine starting fluid) (each not exceeding 1 L capacity) 2.1 UN1950 n/a Only ORM-D Prohibited 2A
Aerosols, nonflammable (each not exceeding 1 L capacity) 2.2 UN1950 n/a Only ORM-D 2B 2B
Aerosols, poison, each not exceeding 1 L capacity 2.2 UN1950 n/a Only ORM-D 2B 2B
Air bag inflators, compressed gas or Air bag modules, compressed gas or Seat-belt pretensioners, compressed gas 2.2 UN3353 n/a Prohibited blank blank
Air bag inflators, pyrotechnic or Air bag modules, pyrotechnic or Seat-belt pretensioners, pyrotechnic 9 UN3268 III Prohibited blank blank
Air, compressed 2.2 UN1002 n/a Only ORM-D 2B 2B
Air, refrigerated liquid (cryogenic liquid) 2.2 UN1003 n/a Prohibited blank blank
Air, refrigerated liquid (cryogenic liquid), non-pressurized 2.2 UN1003 n/a Prohibited blank blank
Aircraft evacuation slides, see Life-saving appliances etc. blank blank blank blank blank blank
Aircraft hydraulic power unit fuel tank (containing a mixture of anhydrous hydrazine and monomethyl hydrazine) (M86 fuel) 3 UN3165 I Prohibited blank blank
Aircraft survival kits, see Life-saving appliances etc. blank blank blank blank blank blank
Alcoholates solution, n.o.s., in alcohol 3 UN3274 II Prohibited blank blank
Alcoholic beverages 3 UN3065 II, III Prohibited (by 18 USC 1716) blank blank
Alcohols, n.o.s. 3 UN1987 I Prohibited blank blank
Alcohols, n.o.s. 3 UN1987 II, III Only ORM-D Prohibited 3A
Alcohols, flammable, toxic, n.o.s. 3 UN1986 I, II, III Prohibited blank blank
Aldehydes, n.o.s. 3 UN1989 I Prohibited blank blank
Aldehydes, n.o.s. 3 UN1989 II, III Only ORM-D Prohibited 3A
Aldehydes, flammable, toxic, n.o.s. 3 UN1988 I, II Prohibited blank blank
Aldehydes, flammable, toxic, n.o.s. 3 UN1988 III Only ORM-D Prohibited 3A
Aldol 6.1 UN2839 II Prohibited blank blank
Aldrin, liquid 6.1 NA2762 II Prohibited blank blank
Aldrin, solid 6.1 NA2761 II Prohibited blank blank
Alkali metal alcoholates, self-heating, corrosive, n.o.s. 4.2 UN3206 II, III Prohibited blank blank
Alkali metal alloys, liquid, n.o.s. 4.3 UN1421 I Prohibited blank blank
Alkali metal amalgam, liquid 4.3 UN1389 I Prohibited blank blank
Alkali metal amalgam, solid 4.3 UN1389 I Prohibited blank blank
Alkali metal amides 4.3 UN1390 II Only ORM-D Prohibited 4A
Alkali metal dispersions, or Alkaline earth metal dispersions 4.3 UN1391 I Prohibited blank blank
Alkaline corrosive liquids, n.o.s., see Caustic alkali liquids, n.o.s. blank blank blank blank blank blank
Alkaline earth metal alcoholates, n.o.s. 4.2 UN3205 II, III Prohibited blank blank
Alkaline earth metal alloys, n.o.s. 4.3 UN1393 II Only ORM-D Prohibited 4A
Alkaline earth metal amalgams 4.3 UN1392 I Prohibited blank blank
Alkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s. 6.1 UN3140 I, II Prohibited blank blank
Alkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s. 6.1 UN3140 III Only ORM-D 6A 6A
Alkaloids, solid, n.o.s. or Alkaloid salts, solid, n.o.s. poisonous 6.1 UN1544 I, II Prohibited blank blank
Alkaloids, solid, n.o.s. or Alkaloid salts, solid, n.o.s. poisonous 6.1 UN1544 III Only ORM-D 6A 6A
Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with more than 5 percent free sulfuric acid 8 UN2584 II Only ORM-D and per 348.2 8A 8A
Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with not more than 5 percent free sulfuric acid 8 UN2586 III Only ORM-D 8A 8A
Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid with more than 5 percent free sulfuric acid 8 UN2583 II Only ORM-D and per 348.2 8A 8A
Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid with not more than 5 percent free sulfuric acid 8 UN2585 III Only ORM-D 8A 8A
Alkylphenols, liquid, n.o.s. (including C2-C12 homologues) 8 UN3145 I Prohibited blank blank
Alkylphenols, liquid, n.o.s. (including C2-C12 homologues) 8 UN3145 II, III Only ORM-D 8A 8A
Alkylphenols, solid, n.o.s. (including C2-C12 homologues) 8 UN2430 I Prohibited blank blank
Alkylphenols, solid, n.o.s. (including C2-C12 homologues) 8 UN2430 II, III Only ORM-D 8A 8A
Alkylsulfuric acids 8 UN2571 II Only ORM-D 8A 8A
Allethrin, see Pesticides, liquid, toxic, n.o.s. blank blank blank blank blank blank
Allyl acetate 3 UN2333 II Prohibited blank blank
Allyl alcohol 6.1 UN1098 I Prohibited blank blank
Allyl bromide 3 UN1099 I Prohibited blank blank
Allyl chloride 3 UN1100 I Prohibited blank blank
Allyl chlorocarbonate, see Allyl chloroformate blank blank blank blank blank blank
Allyl chloroformate 6.1 UN1722 I Prohibited blank blank
Allyl ethyl ether 3 UN2335 II Prohibited blank blank
Allyl formate 3 UN2336 I Prohibited blank blank
Allyl glycidyl ether 3 UN2219 III Only ORM-D Prohibited 3A
Allyl iodide 3 UN1723 II Prohibited blank blank
Allyl isothiocyanate, stabilized 6.1 UN1545 II Prohibited blank blank
Allylamine 6.1 UN2334 I Prohibited blank blank
Allyltrichlorosilane, stabilized 8 UN1724 II Prohibited blank blank
Aluminum alkyl halides 4.2 UN3052 I Prohibited blank blank
Aluminum alkyl hydrides 4.2 UN3076 I Prohibited blank blank
Aluminum alkyls 4.2 UN3051 I Prohibited blank blank
Aluminum borohydride or Aluminum borohydride in devices 4.2 UN2870 I Prohibited blank blank
Aluminum bromide, anhydrous 8 UN1725 II Only ORM-D 8A 8A
Aluminum bromide, solution 8 UN2580 III Only ORM-D 8A 8A
Aluminum carbide 4.3 UN1394 II Only ORM-D Prohibited 4A
Aluminum chloride, anhydrous 8 UN1726 II Only ORM-D 8A 8A
Aluminum chloride, solution 8 UN2581 III Only ORM-D 8A 8A
Aluminum dross, wet or hot Forbidden blank blank Prohibited blank blank
Aluminum ferrosilicon powder 4.3 UN1395 II, III Only ORM-D Prohibited 4A
Aluminum hydride 4.3 UN2463 I Prohibited blank blank
Aluminum, molten 9 NA9260 III Prohibited blank blank
Aluminum, nitrate 5.1 UN1438 III Only ORM-D 5A 5A
Aluminum phosphate solution, see Corrosive liquids, etc. blank blank blank blank blank blank
Aluminum phosphide 4.3 UN1397 I Prohibited blank blank
Aluminum phosphide pesticides 6.1 UN3048 I Prohibited blank blank
Aluminum powder, coated 4.1 UN1309 II, III Only ORM-D Prohibited 4A
Aluminum powder, uncoated 4.3 UN1396 II, III Only ORM-D Prohibited 4A
Aluminum resinate 4.1 UN2715 III Only ORM-D Prohibited 4A
Aluminum silicon powder, uncoated 4.3 UN1398 III Only ORM-D Prohibited 4A
Aluminum smelting by-products or Aluminum remelting by-products 4.3 UN3170 II, III Prohibited blank blank
Amatols, see Explosives, blasting, type B blank blank blank blank blank blank
Amines, flammable, corrosive, n.o.s. or Polyamines, flammable, corrosive, n.o.s. 3 UN2733 I, II Prohibited blank blank
Amines, flammable, corrosive, n.o.s. or Polyamines, flammable, corrosive, n.o.s. 3 UN2733 III Only ORM-D Prohibited 3A
Amines, liquid, corrosive, flammable, n.o.s. or Polyamines, liquid, corrosive, flammable, n.o.s. 8 UN2734 I, II Prohibited blank blank
Amines, liquid, corrosive, n.o.s. or Polyamines, liquid, corrosive, n.o.s. 8 UN2735 I Prohibited blank blank
Amines, liquid, corrosive, n.o.s. or Polyamines, liquid, corrosive, n.o.s. 8 UN2735 II, III Only ORM-D 8A 8A
Amines, solid, corrosive, n.o.s. or Polyamines, solid, corrosive, n.o.s. 8 UN3259 I Prohibited blank blank
Amines, solid, corrosive, n.o.s. or Polyamines, solid, corrosive, n.o.s. 8 UN3259 II, III Only ORM-D 8A 8A
2-Amino-4-chlorophenol 6.1 UN2673 II Prohibited blank blank
2-Amino-5-diethylaminopentane 6.1 UN2946 III Only ORM-D 6A 6A
2-Amino-4,6-Dinitrophenol, wetted with not less than 20 percent water by mass 4.1 UN3317 I Prohibited blank blank
2-(2-Aminoethoxy) ethanol 8 UN3055 III Only ORM-D 8A 8A
N-Aminoethylpiperazine 8 UN2815 III Only ORM-D 8A 8A
Aminophenols (o-; m-; p-) 6.1 UN2512 III Only ORM-D 6A 6A
Aminopropyldiethanolamine, see Amines, etc. blank blank blank blank blank blank
n-Aminopropylmorpholine, see Amines, etc. blank blank blank blank blank blank
Aminopyridines (o-; m-; p-) 6.1 UN2671 II Prohibited blank blank
Ammonia, anhydrous 2.3 UN1005 n/a Prohibited blank blank
Ammonia, anhydrous 2.2 UN1005 n/a Prohibited blank blank
Ammonia solution, relative density between 0.880 and 0.957 at 15° C in water, with more than 10 percent but not more than 35 percent ammonia 8 UN2672 III Only ORM-D and per 348.2 8A 8A
Ammonia solution, relative density less than 0.880 at 15° C in water, with more than 35 percent but not more than 50 percent ammonia 2.2 UN2073 n/a Prohibited blank blank
Ammonia solution, relative density less than 0.880 at 15° C in water, with more than 50 percent ammonia 2.2 UN3318 n/a Prohibited blank blank
Ammonia solution, relative density less than 0.880 at 15° C in water, with more than 50 percent ammonia 2.3 UN3318 n/a Prohibited blank blank
Ammonium arsenate 6.1 UN1546 II Prohibited blank blank
Ammonium azide Forbidden blank blank Prohibited blank blank
Ammonium bifluoride, solid, see Ammonium hydrogendifluoride, solid blank blank blank blank blank blank
Ammonium bifluoride, solution, see Ammonium hydrogendifluoride, solution blank blank blank blank blank blank
Ammonium bromate Forbidden blank blank Prohibited blank blank
Ammonium chlorate Forbidden blank blank Prohibited blank blank
Ammonium dichromate 5.1 UN1439 II Only ORM-D 5A 5A
Ammonium dintro-o-cresolate 6.1 UN1843 II Prohibited blank blank
Ammonium fluoride 6.1 UN2505 III Only ORM-D 6A 6A
Ammonium fluorosilicate 6.1 UN2854 III Only ORM-D 6A 6A
Ammonium fulminate Forbidden blank blank Prohibited blank blank
Ammonium hydrogen sulfate 8 UN2506 II Only ORM-D 8A 8A
Ammonium hydrogendifluoride, solid 8 UN1727 II Only ORM-D 8A 8A
Ammonium hydrogendiflouride, solution 8 UN2817 II Prohibited blank blank
Ammonium hydrogendiflouride, solution 8 UN2817 III Only ORM-D 8A 8A
Ammonium hydrosulfide, solution, see Ammonium sulfide solution blank blank blank blank blank blank
Ammonium hydroxide, see Ammonia solutions, etc. blank blank blank blank blank blank
Ammonium metavanadate 6.1 UN2859 II Prohibited blank blank
Ammonium nitrate fertilizers 5.1 NA2072 III Only ORM-D 5A 5A
Ammonium nitrate fertilizers; uniform non-segregating mixtures of ammonium nitrate with added matter which is inorganic and chemically inert towards ammonium nitrate, with not less than 90 percent ammonium nitrate and not more than 0.2 percent combustible material (including organic material calculated as carbon), or with more than 70 percent but less than 90 percent ammonium nitrate and not more than 0.4 percent total combustible material 5.1 UN2067 III Only ORM-D 5A 5A
Ammonium nitrate fertilizers: uniform non-segregating mixtures of nitrogen/phosphate or nitrogen/potash types or complete fertilizers of nitrogen/phosphate/potash type, with not more than 70 percent ammonium nitrate and not more than 0.4 percent total added combustible material or with not more than 45 percent ammonium nitrate with unrestricted combustible material 9 UN2071 III Only ORM-D 9C 9C
Ammonium nitrate-fuel oil mixture containing only prilled ammonium nitrate and fuel oil 1.5D NA0331 II Prohibited blank blank
Ammonium nitrate, liquid (hot concentrated solution) 5.1 UN2426 n/a Prohibited blank blank
Ammonium nitrate mixed fertilizers 5.1 NA2069 III Only ORM-D 5A 5A
Ammonium nitrate, with more than 0.2 percent combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance 1.1D UN0222 II Prohibited blank blank
Ammonium nitrate, with not more than 0.2 percent of combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance 5.1 UN1942 III Only ORM-D 5A 5A
Ammonium nitrate Forbidden blank blank Prohibited blank blank
Ammonium perchlorate 1.1D UN0402 II Prohibited blank blank
Ammonium perchlorate 5.1 UN1442 II Only ORM-D 5A 5A
Ammonium permanganate Forbidden blank blank Prohibited blank blank
Ammonium persulfate 5.1 UN1444 III Only ORM-D 5A 5A
Ammonium picrate, dry or wetted with less than 10 percent water, by mass 1.1D UN0004 II Prohibited blank blank
Ammonium picrate, wetted with not less than 10 percent water, by mass 4.1 UN1310 I Prohibited blank blank
Ammonium polysulfide, solution 8 UN2818 II Prohibited blank blank
Ammonium polysulfide, solution 8 UN2818 III Only ORM-D 8A 8A
Ammonium polyvanadate 6.1 UN2861 II Prohibited 6A 6A
Ammonium silicofluoride, see Ammonium fluorosilicate blank blank blank blank blank blank
Ammonium sulfide solution 8 UN2683 II Prohibited blank blank
Ammunition, blank, see Cartridges for weapons, blank blank blank blank blank blank blank
Ammunition, illuminating with or without burster, expelling charge, or propelling charge 1.2G UN0171 II Prohibited blank blank
Ammunition, illuminating with or without burster, expelling charge, or propelling charge 1.3G UN0254 II Prohibited blank blank
Ammunition, illuminating with or without burster, expelling charge, or propelling charge 1.4G UN0297 II Prohibited blank blank
Ammunition, incendiary liquid or gel, with burster, expelling charge, or propelling charge 1.3J UN0247 II Prohibited blank blank
Ammunition, incendiary (water-activated contrivances) with burster, expelling charge, or propelling charge, see Contrivances, water-activated, etc. blank blank blank blank blank blank
Ammunition, incendiary, white phosphorus, with burster, expelling charge, or propelling charge 1.2H UN0243 II Prohibited blank blank
Ammunition, incendiary, white phosphorus, with burster, expelling charge, or propelling charge 1.3H UN0244 II Prohibited blank blank
Ammunition, incendiary with or without burster, expelling charge, or propelling charge 1.2G UN0009 II Prohibited blank blank
Ammunition, incendiary with or without burster, expelling charge, or propelling charge 1.3G UN0010 II Prohibited blank blank
Ammunition, incendiary with or without burster, expelling charge, or propelling charge 1.4G UN0300 II